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The default System.Windows.Forms.DataGridViewCellStyle returned by this property has an initial DataGridViewCellStyle.Alignment property value of DataGridViewContentAlignment.MiddleCenter. This value overrides the value specified in the DataGridView.DefaultCellStyle property of the System.Windows.Forms.DataGridView control, but may be overridden by other cell style properties. For more information, see Cell Styles in the Windows Forms DataGridView Control.
When visual styles are enabled, the buttons in a button column are painted using a System.Windows.Forms.ButtonRenderer and cell styles specified through properties such as DataGridViewButtonColumn.DefaultCellStyle have no effect.